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Issue 54, 2017, Issue in Progress
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Simultaneous neutron reflectometry and infrared reflection absorption spectroscopy (IRRAS) study of mixed monolayer reactions at the air–water interface

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Abstract

The simultaneous application of neutron reflectometry (NR) and infrared reflection absorption spectroscopy (IRRAS) to the study of the oxidation kinetics of organic monolayers at the air–water interface is described for the first time. This advance was possible thanks to the development of a new sample environment that includes a gas-delivery system and is compatible with in situ application of the two techniques within the constraints of short-term neutron beam-line access. We studied the oxidation of monolayers of the mono-molecular film palmitoleic acid and of a binary mixture of oleic (OA) and stearic (SA) acids by gas-phase ozone. We contrast the two highly complementary techniques and demonstrate that IRRAS provides key additional insight into the alignment of surfactant molecules at the air–water interface. We highlight the potential of the more economical and widely available IRRAS technique to complement NR studies. We also found an apparent increase of the NR signal upon oxidation of a mixed SA/OA monolayer, as well as evidence of slow intensity fluctuations of the SA-generated IRRAS signal. We demonstrate how simultaneous NR-IRRAS substantially enhances future studies of increasingly complex surfactant mixtures and their atmospheric surface reactions.

Graphical abstract: Simultaneous neutron reflectometry and infrared reflection absorption spectroscopy (IRRAS) study of mixed monolayer reactions at the air–water interface

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Publication details

The article was received on 01 May 2017, accepted on 23 Jun 2017 and first published on 07 Jul 2017


Article type: Paper
DOI: 10.1039/C7RA04900E
Citation: RSC Adv., 2017,7, 34208-34214
  • Open access: Creative Commons BY license
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    Simultaneous neutron reflectometry and infrared reflection absorption spectroscopy (IRRAS) study of mixed monolayer reactions at the air–water interface

    M. W. A. Skoda, B. Thomas, M. Hagreen, F. Sebastiani and C. Pfrang, RSC Adv., 2017, 7, 34208
    DOI: 10.1039/C7RA04900E

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