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Issue 68, 2014
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Stereoselective construction of a key hydroindole precursor of epidithiodiketopiperazine (ETP) natural products

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Abstract

An asymmetric synthetic strategy for constructing the divergent-synthesis monomer of epidithiodiketopiperazine (ETP) natural products has been successfully developed. The functionalized 2,3,3a,4,7,7a-hexahydroindole scaffold was constructed by a diastereoselective inverse electron-demand Diels–Alder (IEDDA) reaction.

Graphical abstract: Stereoselective construction of a key hydroindole precursor of epidithiodiketopiperazine (ETP) natural products

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Article information


Submitted
30 May 2014
Accepted
03 Jul 2014
First published
03 Jul 2014

Chem. Commun., 2014,50, 9690-9692
Article type
Communication
Author version available

Stereoselective construction of a key hydroindole precursor of epidithiodiketopiperazine (ETP) natural products

M. Feng and X. Jiang, Chem. Commun., 2014, 50, 9690
DOI: 10.1039/C4CC04148H

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