A novel rhodium-catalyzed imination of sulfoxides using O-(2,4-dinitrophenyl)hydroxylamine is developed under mild conditions with good functional group tolerance. This method provides an efficient access to free NH-sulfoximines, an important structural unit in a variety of biologically active compounds.
J. Miao, N. G. J. Richards and H. Ge, Chem. Commun., 2014, 50, 9687 DOI: 10.1039/C4CC04349A
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