Issue 41, 2013
From the journal:

Organic & Biomolecular Chemistry

α-Vinylation of amides with arylacetylenes: synthesis of allylamines under metal-free conditions†

Manman Sun,a   Huandong Wua  and  Weiliang Bao*a  

* Corresponding authors

a Department of Chemistry, Zhejiang University (Xixi Campus), Hangzhou 310028, People's Republic of China
E-mail: wlbao@css.zju.edu.cn
Fax: +86-571-88273814
Tel: +86-571-88273814

Abstract

A novel methodology for the α-vinylation of amides with arylacetylenes under metal-free conditions has been introduced. This methodology provides a new protocol to synthesize allylamines. In each product, the amount of the cis-isomer was more than that of the trans-isomer.

Graphical abstract: α-Vinylation of amides with arylacetylenes: synthesis of allylamines under metal-free conditions

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Article information

DOI
https://doi.org/10.1039/C3OB41450G
Article type
Communication
Submitted
15 Jul 2013
Accepted
30 Aug 2013
First published
30 Aug 2013

Org. Biomol. Chem., 2013,11, 7076-7079

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α-Vinylation of amides with arylacetylenes: synthesis of allylamines under metal-free conditions

M. Sun, H. Wu and W. Bao, Org. Biomol. Chem., 2013, 11, 7076 DOI: 10.1039/C3OB41450G

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