Issue 41, 2013
From the journal:

Organic & Biomolecular Chemistry

Lewis base catalyzed asymmetric substitution/Diels–Alder cascade reaction: a rapid and efficient construction of enantioenriched diverse tricyclic heterocycles†

Gong-Feng Zou,‡a   Feng Pan‡a  and  Wei-Wei Liao*a  

* Corresponding authors

a Department of Organic Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China
E-mail: wliao@jlu.edu.cn
Tel: (+86) 0431-85168420

Abstract

The first tertiary amine catalyzed asymmetric allylic amination/cycloaddition cascade sequence has been developed, which provided a novel protocol to construct enantioenriched azapolyheterocycles under mild reaction conditions efficiently (up to 95% ee, endo/exo >20 : 1).

Graphical abstract: Lewis base catalyzed asymmetric substitution/Diels–Alder cascade reaction: a rapid and efficient construction of enantioenriched diverse tricyclic heterocycles

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Article information

DOI
https://doi.org/10.1039/C3OB41454J
Article type
Communication
Submitted
15 Jul 2013
Accepted
03 Sep 2013
First published
03 Sep 2013

Org. Biomol. Chem., 2013,11, 7080-7083

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Lewis base catalyzed asymmetric substitution/Diels–Alder cascade reaction: a rapid and efficient construction of enantioenriched diverse tricyclic heterocycles

G. Zou, F. Pan and W. Liao, Org. Biomol. Chem., 2013, 11, 7080 DOI: 10.1039/C3OB41454J

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