Issue 19, 2013

Stepwise replacement of nickel with cobalt ions in a [Ni6] cluster

Abstract

Polydentate ligands were used to support planar methoxo-bridged {Ni6−xCox} (x = 0, 1 or 2) clusters which were structurally characterized by single crystal analyses. The homometallic {Ni6} complex displayed overall ferrimagnetic interactions between metal centres, and increasing the cobalt content led to a proportional increase in ac-response.

Graphical abstract: Stepwise replacement of nickel with cobalt ions in a [Ni6] cluster

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2013
Accepted
21 Mar 2013
First published
22 Mar 2013

Dalton Trans., 2013,42, 6701-6704

Stepwise replacement of nickel with cobalt ions in a [Ni6] cluster

G. N. Newton, H. Sato, T. Shiga and H. Oshio, Dalton Trans., 2013, 42, 6701 DOI: 10.1039/C3DT50429H

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