Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

Ross McLellan; Stephanie M. Taylor; Ruaraidh D. McIntosh; Euan K. Brechin; Scott J. Dalgarno

doi:10.1039/C3DT50294E

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Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn^IVMn^III dimer†‡

Ross McLellan,^a Stephanie M. Taylor,^b Ruaraidh D. McIntosh,^a Euan K. Brechin*^b and Scott J. Dalgarno*^a

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* Corresponding authors

^a Institute of Chemical Sciences, Heriot-Watt University, Riccarton, Edinburgh, Scotland, UK
E-mail: S.J.Dalgarno@hw.ac.uk
Fax: +44 (0)131-451-3180
Tel: +44 (0)131-451-8025

^b EaStCHEM School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK
E-mail: ebrechin@staffmail.ed.ac.uk
Fax: +44 (0)131-650-6453
Tel: +44 (0)131-650-7545

Abstract

A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH₂) have been utilised in the facile synthesis of a Mn^IIIMn^IV dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

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Article information

DOI: https://doi.org/10.1039/C3DT50294E
Article type: Communication
Submitted: 29 Jan 2013
Accepted: 22 Mar 2013
First published: 22 Mar 2013

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Dalton Trans., 2013,42, 6697-6700

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Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn^IVMn^III dimer

R. McLellan, S. M. Taylor, R. D. McIntosh, E. K. Brechin and S. J. Dalgarno, Dalton Trans., 2013, 42, 6697 DOI: 10.1039/C3DT50294E

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Dalton Transactions