Issue 19, 2013
From the journal:

Dalton Transactions

Facile synthesis of the new tripodal tetraamineligandtris(thiazolylmethyl) amine, and full characterization of two ferrous complexes†

Aurore Thibon,a   Lydia Karmazin-Brelotb  and  Dominique Mandon*a  

* Corresponding authors

a Laboratoire de Chimie Biomimétique des Métaux de Transition, UMR CNRS 7177, Institut de Chimie de Strasbourg, Université de Strasbourg, Bâtiment Le Bel, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France
E-mail: mandon@unistra.fr
Fax: + 33 (0)368 85 14 38

b Service de Radiocristallographie, UMR CNRS no. 7177, Institut de Chimie de Strasbourg et Université de Strasbourg, 1, rue Blaise Pascal, BP 296/R8 67008 Strasbourg cedex, France

Abstract

We report in this communication the facile synthesis of the new tris(thiazolylmethyl)amine TTA ligand and the full characterization in solution and in the solid state of two ferrous complexes, [(TTA)FeCl2] and [(TTA)Fe(OTf)2]. TTA, the first example of a simple tris(thiazolemethyl)amine chelate – the second one only within this class of tripods – exerts a weak ligand field and the tertiary amine is weakly bound to the metal centre.

Graphical abstract: Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexes

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Article information

DOI
https://doi.org/10.1039/C3DT50484K
Article type
Communication
Submitted
22 Feb 2013
Accepted
15 Mar 2013
First published
15 Mar 2013

Dalton Trans., 2013,42, 6705-6707

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Facile synthesis of the new tripodal tetraamine ligand tris(thiazolylmethyl) amine, and full characterization of two ferrous complexes

A. Thibon, L. Karmazin-Brelot and D. Mandon, Dalton Trans., 2013, 42, 6705 DOI: 10.1039/C3DT50484K

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