Issue 26, 2011
From the journal:

Chemical Communications

A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties†

Jin Jin,a   Weiyin Wang,a   Yanhua Liu,a   Hongwei Hou*a  and  Yaoting Fana  

* Corresponding authors

a Department of Chemistry, Zhengzhou University, Henan 450052, PR China
E-mail: houhongw@zzu.edu.cn
Fax: +86-371-67761744
Tel: +86-371-67761744

Abstract

The first hexagonal octadecanuclear Ag macrocycle [Ag18(TTTMB)12](NO3)18·30H2O has been hydrothermally synthesized. The outside and inner diameters of the unprecedented architecture are about 27.72(13) Å and 15.37(7) Å, respectively. This complex displays a huge increase in the intensity and lifetime of phosphorescence with decreasing temperature.

Graphical abstract: A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

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Article information

DOI
https://doi.org/10.1039/C1CC12142A
Article type
Communication
Submitted
14 Apr 2011
Accepted
19 May 2011
First published
31 May 2011

Chem. Commun., 2011,47, 7461-7463

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A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

J. Jin, W. Wang, Y. Liu, H. Hou and Y. Fan, Chem. Commun., 2011, 47, 7461 DOI: 10.1039/C1CC12142A

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