Issue 10, 2008
From the journal:

Dalton Transactions

Effect of the substituents on the spin coupling between iminosemiquinone π-radicals mediated by diamagnetic metal ions: l.s. Co(iii)vsGa(iii)†‡§

Phalguni Chaudhuri,*a   Rita Wagner,a   Ulrich Pieper,a   Biplab Biswasa  and  Thomas Weyhermüllera  

* Corresponding authors

a Max-Planck-Institute for Bioinorganic Chemistry, Stiftstrasse 34-36, Mülheim an der Ruhr, Germany
E-mail: Chaudh@mpi-muelheim.mpg.de

Abstract

Exchange coupling between the radical iminosemiquinone ligands changes from ferromagnetic to antiferromagnetic in l.s. Co(III) complexes 1–5, whereas the same coupling in Ga(III) complexes 6–8 is always antiferromagnetic

Graphical abstract: Effect of the substituents on the spin coupling between iminosemiquinone π-radicals mediated by diamagnetic metal ions: l.s. Co(iii)vsGa(iii)

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Article information

DOI
https://doi.org/10.1039/B717004A
Article type
Communication
Submitted
02 Nov 2007
Accepted
03 Jan 2008
First published
24 Jan 2008

Dalton Trans., 2008, 1286-1288

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Effect of the substituents on the spin coupling between iminosemiquinone π-radicals mediated by diamagnetic metal ions: l.s. Co(III)vsGa(III)

P. Chaudhuri, R. Wagner, U. Pieper, B. Biswas and T. Weyhermüller, Dalton Trans., 2008, 1286 DOI: 10.1039/B717004A

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