Issue 10, 2008
From the journal:

Dalton Transactions

Crystallization induced chiral locking of a central labile core in a star-shaped tetra-nuclear complex†

Hisako Sato,a   Yuka Furuno,b   Yutaka Fukuda,b   Kentaro Okamotob  and  Akihiko Yamagishi*b  

* Corresponding authors

a The University of Tokyo, Tokyo, Japan and PRESTO, JST, Japan
E-mail: h-sato@eps.u-tokyo.ac.jp
Fax: +81-3-5841-4019
Tel: +81-3-5841-4019

b Ochanomizu University, Tokyo, Japan
E-mail: yamagishi.akihiko@ocha.ac.jp
Fax: +81-3-5978-5575
Tel: +81-3-5978-5575

Abstract

The central labile Al(III) core of a star-shaped tetra-nuclear metal complex, [{Δ-Ru(III)(acac)2(taet)}3Al(III)] (acac = acetylacetonato; taet = tetraacetylethanato), which was synthesized by reacting Δ-[Ru(III)(acac)2(taetH)] (taetH = singly protonated taet) with an Al(III) ion in solution, was found to be locked as a Λ-form in the solid state.

Graphical abstract: Crystallization induced chiral locking of a central labile core in a star-shaped tetra-nuclear complex

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Article information

DOI
https://doi.org/10.1039/B717429B
Article type
Communication
Submitted
12 Nov 2007
Accepted
07 Jan 2008
First published
01 Feb 2008

Dalton Trans., 2008, 1283-1285

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Crystallization induced chiral locking of a central labile core in a star-shaped tetra-nuclear complex

H. Sato, Y. Furuno, Y. Fukuda, K. Okamoto and A. Yamagishi, Dalton Trans., 2008, 1283 DOI: 10.1039/B717429B

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