Issue 24, 2005
From the journal:

Chemical Communications

Ionic diamine rhodium(i) complexes—highly active catalysts for the hydroformylation of olefins†

Jai Jun Kima  and  Howard Alper*a  

* Corresponding authors

a Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Canada
E-mail: howard.alper@uottawa.ca
Fax: +1 613 562 5871
Tel: +1 613 562 5189

Abstract

Rhodium(I) complexes composed of an anionic rhodium centre containing chloride ligands, and a cationic rhodium centre coordinated by a diamine ligand, were synthesized and characterized. These complexes are able to catalyze the hydroformylation reaction under mild reaction conditions in excellent activity and regioselectivity, and in the absence of a phosphorus ligand.

Graphical abstract: Ionic diamine rhodium(i) complexes—highly active catalysts for the hydroformylation of olefins

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Article information

DOI
https://doi.org/10.1039/B502435H
Article type
Communication
Submitted
16 Feb 2005
Accepted
14 Apr 2005
First published
09 May 2005

Chem. Commun., 2005, 3059-3061

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Ionic diamine rhodium(I) complexes—highly active catalysts for the hydroformylation of olefins

J. J. Kim and H. Alper, Chem. Commun., 2005, 3059 DOI: 10.1039/B502435H

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