Issue 24, 2005
From the journal:

Chemical Communications

Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

Jesus Ramírez,a   Rosa Corberán,b   Mercedes Sanaú,c   Eduardo Peris*b  and  Elena Fernandez*a  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Pça. Imperial Tàrraco 1, Tarragona, Spain
E-mail: elenaf@quimica.urv.es
Fax: 34 977 559563
Tel: 34 977 558046

b Dpt. Química Inorgànica i Orgànica, Universitat Jaume I, Av Vicente Sos Baynat s/n, Castellón, Spain
E-mail: eperis@qio.uji.es

c Dpt. Química Inorgánica, Universitat de València, Burjassot

Abstract

Catalytic diboration of internal and terminal alkenes with Ag(I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.

Graphical abstract: Unprecedented use of silver(i) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

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Article information

DOI
https://doi.org/10.1039/B503239C
Article type
Communication
Submitted
04 Mar 2005
Accepted
14 Apr 2005
First published
06 May 2005

Chem. Commun., 2005, 3056-3058

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Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

J. Ramírez, R. Corberán, M. Sanaú, E. Peris and E. Fernandez, Chem. Commun., 2005, 3056 DOI: 10.1039/B503239C

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