Issue 15, 2003
From the journal:

Chemical Communications

Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

Ronan M. Bellabarba,*a   Robert P. Toozea  and  Alexandra M. Z. Slawinb  

* Corresponding authors

a Sasol Technology (UK), Purdie Building, North Haugh, St Andrews, Fife, UK
E-mail: ronan.bellabarba@sasol.com
Fax: +27 (0)11 5226309
Tel: +44 (0)1334 460 934

b School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, Fife, UK
E-mail: amzs@st-andrews.ac.uk
Fax: +44 (0)1334 463384
Tel: +44 (0)1334 467280

Abstract

The novel complex (tbpx)PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.

Graphical abstract: Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

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Article information

DOI
https://doi.org/10.1039/B305854A
Article type
Communication
Submitted
27 May 2003
Accepted
12 Jun 2003
First published
26 Jun 2003

Chem. Commun., 2003, 1916-1917

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Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

R. M. Bellabarba, R. P. Tooze and A. M. Z. Slawin, Chem. Commun., 2003, 1916 DOI: 10.1039/B305854A

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