Issue 15, 2003
From the journal:

Chemical Communications

Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes†

Audrey Moores,a   Nicolas Mézailles,a   Louis Ricard,a   François Matheya  and  Pascal Le Floch*a  

* Corresponding authors

a Department of Chemistry, Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128, Palaiseau Cedex, France
E-mail: lefloch@poly.polytechnique.fr
Fax: 33.1.69.33.39.90
Tel: 33.1.69.33.45.70

Abstract

Reaction of a tetraphenyl-1,2-diphosphinyl dianion with [FeCl2(THF)1.5] or [Ru(COD)(acac)2] yields dianionic complexes which further react with Ph3SnCl to afford the corresponding bis(1,4-diphosphabutadiene) complexes.

Graphical abstract: Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes

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Article information

DOI
https://doi.org/10.1039/B304243J
Article type
Communication
Submitted
17 Apr 2003
Accepted
10 Jun 2003
First published
26 Jun 2003

Chem. Commun., 2003, 1914-1915

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Neutral and dianionic iron and ruthenium 1,4-diphosphabutadiene complexes

A. Moores, N. Mézailles, L. Ricard, F. Mathey and P. Le Floch, Chem. Commun., 2003, 1914 DOI: 10.1039/B304243J

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