Issue 9, 1999

The iron-mediated intramolecular addition of carboxylates to conjugated dienes

Abstract

Treatment of carboxylic acid functionalized (η4-diene)Fe(CO)3 complexes with 3.0 equiv. of NOBF4 in the presence of Et3N generates γ- and δ-lactones containing an α,β-unsaturated aldehyde or oxime functionality after NO+ insertion.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 805-806

The iron-mediated intramolecular addition of carboxylates to conjugated dienes

M. P. Yeh, L. Chuang, Y. Hsieh and M. Tsai, Chem. Commun., 1999, 805 DOI: 10.1039/A901628G

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