A porphyrin with a β-fused 3-sulfolene on one of the pyrroles acts as a porphodimethylidene precusor which can be used for a variety of Diels–Alder cycloaddition reactions.
M. J. Gunter and H. Tang, Chem. Commun., 1999, 803 DOI: 10.1039/A901446B
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