Issue 4, 1997
From the journal:

Chemical Communications

Reaction of furans with trithiazyl trichloride: new synthesis of isothiazoles

Xiao-Lan Duan,   Charles W. Rees  and  Tai-Yuen Yue  

Abstract

Trithiazyl trichloride 1 converts 2,5-disubstituted furans into isothiazoles (e.g. 3, 6, 7) regiospecifically and in good yield, providing a new, one-step synthesis of isothiazoles, for which a novel mechanism involving formation and ring-opening of a β-thiazylfuran 4 is proposed.

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Article information

DOI
https://doi.org/10.1039/A608345E
Article type
Paper

Chem. Commun., 1997, 367-368

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Reaction of furans with trithiazyl trichloride: new synthesis of isothiazoles

X. Duan, C. W. Rees and T. Yue, Chem. Commun., 1997, 367 DOI: 10.1039/A608345E

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