Issue 4, 1997
From the journal:

Chemical Communications

Trimethylsilyl chloride-accelerated reduction and pinacol coupling of carbonyl compounds by means of samarium diiodide

Toshio Honda  and  Miho Katoh  

Abstract

The combination of samarium diiodide (SmI 2 ) and trimethylsilyl chloride (Me 3 SiCl) in THF–HMPA is found to accelerate the reduction of sterically hindered and enolisable ketones, and also to accelerate pinacolisation of the carbonyl compounds depending on the reaction conditions.

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Article information

DOI
https://doi.org/10.1039/A607774I
Article type
Paper

Chem. Commun., 1997, 369-370

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Trimethylsilyl chloride-accelerated reduction and pinacol coupling of carbonyl compounds by means of samarium diiodide

T. Honda and M. Katoh, Chem. Commun., 1997, 369 DOI: 10.1039/A607774I

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