From monomeric iminosilane to a monomeric aminoalane: synthesis and crystal structures
Abstract
The reaction between the iminosilane R
2
Si![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NR′
[R = CMe
3
, R′= Si(CMe
3
)
2
Ph] 1 and
AlMe
3
in n-hexane at -78 °C affords the
first monomeric aminodimethylalane
Me
2
AlN(R′)R″ [R″=
Si(CMe
3
)
2
Me] 2; the crystal structure of 2 is
presented.
NR′
[R = CMe
3
, R′= Si(CMe
3
)
2
Ph] 1 and
AlMe
3
in n-hexane at -78 °C affords the
first monomeric aminodimethylalane
Me
2
AlN(R′)R″ [R″=
Si(CMe
3
)
2
Me] 2; the crystal structure of 2 is
presented.
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