Issue 10, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolation and X-ray structures of the hexamethylphosphoramide (hmpa)-coordinated lanthanide(II) diiodide complexes [Sml2(hmpa)4] and [Yb(hmpa)4(thf)2]I2

Zhaomin Hou  and  Yasuo Wakatsuki  

Abstract

Reaction of samarium diiodide (Sml2) with hexamethylphosphoramide (hmpa) in tetrahydrofuran (thf) gave [Sml2(hmpa)4]1 after recrystallization from toluene, while in the case of Ybl2, crystals of [Yb(hmpa)4(thf)2]I22 were obtained from thf; both 1 and 2 have been structurally characterized and the influence of hmpa on the reactivity of Sml2 is discussed.

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Article information

DOI
https://doi.org/10.1039/C39940001205
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1205-1206

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Isolation and X-ray structures of the hexamethylphosphoramide (hmpa)-coordinated lanthanide(II) diiodide complexes [Sml2(hmpa)4] and [Yb(hmpa)4(thf)2]I2

Z. Hou and Y. Wakatsuki, J. Chem. Soc., Chem. Commun., 1994, 1205 DOI: 10.1039/C39940001205

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