Issue 10, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Facile formation of a bridging cyclooctatrieneyne ligand; synthesis and molecular structure of [{η-C8H6(SiMe3)2}Zr{CH(SiMe3)2}{µ-η8 : η2-C8H4(SiMe3)2}Zr{CH(SiMe3)2}]

F. Geoffrey N. Cloke,   Peter B. Hitchcock  and  Stephen C. P. Joseph  

Abstract

The reaction between the bridging chloride dimer [{Zr(η-COT″)Cl2}2][COT″= 1,4-bis(trimethylsilyl)cyclooctatetraene] and [LiCH(SiMe3)2] affords the title complex, whose X-ray structure reveals a bridging cyclooctatrieneyne ligand resulting from double hydrogen abstraction from a COT ring.

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Article information

DOI
https://doi.org/10.1039/C39940001207
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1207-1208

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Facile formation of a bridging cyclooctatrieneyne ligand; synthesis and molecular structure of [{η-C8H6(SiMe3)2}Zr{CH(SiMe3)2}{µ-η8 : η2-C8H4(SiMe3)2}Zr{CH(SiMe3)2}]

F. G. N. Cloke, P. B. Hitchcock and S. C. P. Joseph, J. Chem. Soc., Chem. Commun., 1994, 1207 DOI: 10.1039/C39940001207

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