Issue 24, 1992
From the journal:

Journal of the Chemical Society, Chemical Communications

New, chiral silylated organophosphorus(III) reagents: syntheses and applications in the asymmetric phosphorylation of aldehydes

Vivienne Sum,   Anita J. Davies  and  Terence P. Kee  

Abstract

The new silylated organophosphorus(III) compounds, (1R,2S)-(O,N-ephedrine)POSiR3(R3= Ph3, ButMe2, Et3) have been synthesised and shown to react with benzaldehyde to afford the phosphonate esters (1R,2S)-(O,N-ephedrine)P([double bond, length as m-dash]O)CHPh(OSiR3) with good stereoselectivity.

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Article information

DOI
https://doi.org/10.1039/C39920001771
Article type
Paper

J. Chem. Soc., Chem. Commun., 1992, 1771-1773

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New, chiral silylated organophosphorus(III) reagents: syntheses and applications in the asymmetric phosphorylation of aldehydes

V. Sum, A. J. Davies and T. P. Kee, J. Chem. Soc., Chem. Commun., 1992, 1771 DOI: 10.1039/C39920001771

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