Methyl viologen radical cation reduces the 2E excited state of trans-Cr([14]aneN4)(NH3)23+ in acidic solutions to yield a novel chromium(II) macrocycle, trans-Cr([14]aneN4)(H2O)22+, as a final product.
A. Bakac and J. H. Espenson, J. Chem. Soc., Chem. Commun., 1990, 1646 DOI: 10.1039/C39900001646
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