Samples of β-alanine stereospecifically labeled with deuterium in each of the four C–H bonds have been synthesized; these been used to show that, in the first step of uracil metabolism, the pyrimidine is reduced by dihydrouracil dehydrogenase with overall trans-addition of hydrogen at the si-face at C-6 and the si-face at C-5.
D. Gani and D. W. Young, J. Chem. Soc., Chem. Commun., 1983, 576 DOI: 10.1039/C39830000576
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