The compound [B10H13PPh2]is remarkably acidic; n.m.r. studies now show that its conjugate base [B10H12PPh2]– derives its stability from an arachno-decaboranyl cluster structure with, uniquely, a bridging {Ph2P} moiety between the B(6) and B(9) positions.
M. A. Beckett and J. D. Kennedy, J. Chem. Soc., Chem. Commun., 1983, 575 DOI: 10.1039/C39830000575
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