Issue 10, 1983

Study of the Wallach rearrangement in the phenylazoxypyridine series. Differing reactivity of α- and β-azoxy isomers

Abstract

The rearrangement of 4-(phenyl-β-azoxy)pyridine to 4-hydroxyphenylazopyridine has been investigated in H2SO4 media under conditions where the α-azoxy isomer is virtually unreactive; a mechanism involving a tricationic reaction intermediate is proposed

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 578-579

Study of the Wallach rearrangement in the phenylazoxypyridine series. Differing reactivity of α- and β-azoxy isomers

E. Buncel and S. Keum, J. Chem. Soc., Chem. Commun., 1983, 578 DOI: 10.1039/C39830000578

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