Photoelectron spectroscopic studies of the trimethanoanthracenes have revealed a large π orbital interaction through six bonds, an apparent violation of the trans rule and a new and effective way by which a CH2 group can act as a through-bond relay.
F. S. Jørgensen, M. N. Paddon-Row and H. K. Patney, J. Chem. Soc., Chem. Commun., 1983, 573 DOI: 10.1039/C39830000573
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