Issue 17, 1980

Reactions of CS2 with metal cluster carbonyls of the iron triad; synthesis and X-ray structure of [Fe4(CO)12(CS)S]

Abstract

Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 812-813

Reactions of CS2 with metal cluster carbonyls of the iron triad; synthesis and X-ray structure of [Fe4(CO)12(CS)S]

P. V. Broadhurst, B. F. G. Johnson, J. Lewis and P. R. Raithby, J. Chem. Soc., Chem. Commun., 1980, 812 DOI: 10.1039/C39800000812

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