Issue 17, 1980

Carbon dioxide co-ordination chemistry: preparation and X-ray crystal structure of the methoxycarbonyl complex [IrCl(CO2Me)-(Me2PCH2CH2PMe2)2]FSO from a CO adduct

Abstract

[IrCl(CO2Me)(dmpe)2]FSO3(dmpe = Me2PCH2-CH2PMe2) is made by the reaction of Ir(dmpe)2Cl·CO2 with MeFSO3 and its structure has been determined by X-ray crystallography; this is the first transformation of a well defined CO2 ligand into an organic species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 813-814

Carbon dioxide co-ordination chemistry: preparation and X-ray crystal structure of the methoxycarbonyl complex [IrCl(CO2Me)-(Me2PCH2CH2PMe2)2]FSO from a CO adduct

R. L. Harlow, J. B. Kinney and T. Herskovitz, J. Chem. Soc., Chem. Commun., 1980, 813 DOI: 10.1039/C39800000813

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