Cyclopentadienyldimethylborane and pentamethylcyclopentadienyldimethylborane have been synthesized; their n.m.r. spectra indicate fluxional behaviour formally described as a [1,5]sigmatropic migration of the Me2B species.
H. D. Johnson, T. W. Hartford and C. W. Spangler, J. Chem. Soc., Chem. Commun., 1978, 242a DOI: 10.1039/C3978000242A
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