Treatment of 20β-hydroxy-18-methyl-18-oxosteroids with silica formed the stable enol ethers, while reaction with lead tetra-acetate formed the stable acetoxylated enol ethers instead of the expected α-acetoxy-ketones.
G. R. Lenz, J. Chem. Soc., Chem. Commun., 1978, 241 DOI: 10.1039/C39780000241
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