Regiospecific methods for the preparation of islandicin and digitopurpone monomethyl ethers, the tricyclic precursors of daunomycinone and adriamycinone, are described.
R. D. Gleim, S. Trenbeath, F. Suzuki and C. J. Sih, J. Chem. Soc., Chem. Commun., 1978, 242b DOI: 10.1039/C3978000242B
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