Issue 7, 1977

Preparation, X-ray crystal structure analysis, and reactions of a novel, hydroxo-bridged, tetranuclear, π-arene ruthenium(II) quadrivalent cation [{(η6-C6H6)Ru(OH)}4](SO4)2·12H2O

Abstract

Reaction of [{(η6-C6H6)RuCl2}2] with aqueous sodium carbonate (1 : 2 molar ratio) and excess of sodium sulphate gives the title compound (II) whose structure has been determined by X-ray diffraction; a mechanism of formation and some reactions of (II) are also outlined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 222-223

Preparation, X-ray crystal structure analysis, and reactions of a novel, hydroxo-bridged, tetranuclear, π-arene ruthenium(II) quadrivalent cation [{(η6-C6H6)Ru(OH)}4](SO4)2·12H2O

R. O. Gould, C. L. Jones, D. R. Robertson and T. A. Stephenson, J. Chem. Soc., Chem. Commun., 1977, 222 DOI: 10.1039/C39770000222

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