Gas-phase and solution n.m.r. spectral studies of beryllium borohydride, Be(BH4)2, indicate that is contains magnetically equivalent BH4 groups which undergo rapid internal hydrogen exchange; previously postulated triangular boron–beryllium–boron molecular configurations are inconsistent with the n.m.r. data.
D. F. Gaines, J. L. Walsh and D. F. Hillenbrand, J. Chem. Soc., Chem. Commun., 1977, 224 DOI: 10.1039/C39770000224
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