A new, general synthesis of o-benzylanilines (2-aminodiphenylmethanes) from anilines has been developed, which involves the sequential reaction of an aniline with (i) t-butyl hypochlorite, (ii) phenyl benzyl sulphide, and (iii) sodium methoxide, followed by desulphurization with lithium aluminium hydride or Raney-nickel.
P. G. Gassman and H. R. Drewes, J. Chem. Soc., Chem. Commun., 1973, 488 DOI: 10.1039/C39730000488
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