Solution and single-crystal Raman spectra of potassium hexacyanoferrate(III)
Abstract
All the Raman-active modes of [Fe(CN6)]3– have been observed in aqueous solution. For single-crystals (ambient and ca. 160 K) the predictions of factor-group analysis are largely borne out by experiment, as is most of the Raman spectrum calculated by Nakagawa and Shimanouchi. Bonding in the crystal is discussed.
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