Issue 2, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Chloride and bromide complexes of cadmium and lead in aqueous melts of NH4NO3,xH2O

R. M. Nikolić  and  I. J. Gal  

Abstract

The formation constants of species CdCl+, CdCl2, CdBr+, CdBr2, PbCl+, PbCl2, PbBr+, and PbBr2 in aqueous melts of composition NH4NO3,xH2O (x= 1·5, 2, and 3) are evaluated from e.m.f. measurements of suitable concentration cells in the temperature range 40–70 °C. The results are interpreted in terms of a quasi-lattice model of aqueous melts. Standard enthalpy changes for complex formation are calculated and compared with data obtained in sodium nitrate melts.

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Article information

DOI
https://doi.org/10.1039/DT9720000162
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 162-165

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Chloride and bromide complexes of cadmium and lead in aqueous melts of NH4NO3,xH2O

R. M. Nikolić and I. J. Gal, J. Chem. Soc., Dalton Trans., 1972, 162 DOI: 10.1039/DT9720000162

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