Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Identification of syn- and anti-isomers of a cis-co-ordinated dithioether ligand by proton magnetic resonance spectroscopy

H. A. O. Hill  and  K. A. Simpson  

Abstract

The syn- and anti-isomers of a cis-co-ordinated dithioether ligand in the complex Pd(EtS·CH2·CO·N·[CH2]3·-N·CO·CH2·SPh) have been identified by 1H n.m.r. spectroscopy and the thermodynamic parameters of isomerisation have been measured. The 1H n.m.r. spectra showed the presence of two isomers in the complexes Pd[CH2(CH2·N·-CO·CH2·SPh)2] and Pd[CH2(CH2·N·CO·CH2·SEt)2].

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Article information

DOI
https://doi.org/10.1039/J19700003266
Article type
Paper

J. Chem. Soc. A, 1970, 3266-3269

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Identification of syn- and anti-isomers of a cis-co-ordinated dithioether ligand by proton magnetic resonance spectroscopy

H. A. O. Hill and K. A. Simpson, J. Chem. Soc. A, 1970, 3266 DOI: 10.1039/J19700003266

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