SCHEDULED MAINTENANCE
The formation of caracurine-II methochloride from toxiferine-I requires oxygen and acid. Studies of the chemistry of caracurine-II lead to a partial structural assignment which requires only the siting of one bond to give the complete constitution (XI). This is achieved by n.m.r. studies.
The mechanism by which caracurine-II methochloride is formed from toxiferine-I is discussed briefly.
A. R. Battersby, H. F. Hodson, G. V. Rao and D. A. Yeowell, J. Chem. Soc. C, 1967, 2335 DOI: 10.1039/J39670002335
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