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Issue 0, 1967
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Complexes of mercury. Part III. X-Ray analysis of dichlorobis-(1,4-thioxan)mercury(II)

Abstract

Dichlorobis-(1,4-thioxan)mercury(II) crystallises in the orthorhombic system, space group Pn21a, with four molecules of C8H16Cl2HgO2S2 in a cell of dimensions a= 15·31, b= 19·69, c= 4·33 Å. The mercury atom is co-ordinated in a distorted tetrahedral manner by two sulphur atoms at an average distance of 2·57 Å and two chlorine atoms at an average distance of 2·48 Å. The angles S–Hg–S and Cl–Hg–Cl are 115 and 114°, respectively. Each thioxan molecule is in the chair conformation with the S–Hg bond oriented equatorially.

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Article type: Paper
DOI: 10.1039/J19670000271
J. Chem. Soc. A, 1967, 271-275

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    Complexes of mercury. Part III. X-Ray analysis of dichlorobis-(1,4-thioxan)mercury(II)

    R. S. McEwen and G. A. Sim, J. Chem. Soc. A, 1967, 271
    DOI: 10.1039/J19670000271

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