The hydroxyl n.m.r. frequency of methyl cellosolve (2-methoxyethanol) has been measured as a function of concentration and temperature, and the temperature-dependence of the frequencies of pure methanol, ethanol, and t-butyl alcohol have also been investigated. The data are analysed to provide the size and shape of the hydrogen-bonded aggregates and the enthalpies of bonding.
J. Feeney and S. M. Walker, J. Chem. Soc. A, 1966, 1148 DOI: 10.1039/J19660001148
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