Issue 4, 2015

Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO2 capture

Abstract

Open metal sites are devised to dangle on cobalt trigonal prismatic secondary building units (SBUs) of a porous MOF, when a rigid octacarboxylate ligand, 1,3,6,8-tetra(3,5-dicarboxylphenyl)pyrene, assembled with Co(NO3)2 under solvothermal conditions. The functional role of dangled open metal sites is exploited for CO2 capture studies.

Graphical abstract: Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO2 capture

Supplementary files

Article information

Article type
Research Article
Submitted
28 Dis 2014
Accepted
23 Jan 2015
First published
26 Jan 2015

Inorg. Chem. Front., 2015,2, 369-372

Open metal sites dangled on cobalt trigonal prismatic clusters within porous MOF for CO2 capture

W. Gao, S. Palakurty, L. Wojtas, Y. Chen and S. Ma, Inorg. Chem. Front., 2015, 2, 369 DOI: 10.1039/C4QI00240G

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