Issue 10, 2024

Polyoxometalate nanocluster-infused triple IPN hydrogels for excellent microplastic removal from contaminated water: detection, photodegradation, and upcycling

Abstract

Microplastic (MP) pollution pervades global ecosystems, originating from improper plastic disposal and fragmentation due to factors like hydrolysis and biodegradation. These minute particles, less than 5 mm in size, have become omnipresent, impacting terrestrial, freshwater, and marine environments worldwide. Their ubiquity poses severe threats to marine life by causing physical harm and potentially transferring toxins through the food chain. Addressing this environmental crisis necessitates a sustainable strategy. Our proposed solution involves a highly efficient copper substitute polyoxometalate (Cu-POM) nanocluster infused triple interpenetrating polymer network (IPN) hydrogel, comprising chitosan (CS), polyvinyl alcohol (PVA), and polyaniline (PANI) (referred to as pGel@IPN) for mitigating MP contamination from water. This 3D IPN architecture, incorporating nanoclusters, also enhances the hydrogel's photodegradation capabilities. Our scalable approach offers a sustainable strategy to combat MPs in water bodies, as demostrated by the adsorption behaviors on the hydrogel matrix under varying conditions, simulating real-world scenarios. Evaluations of physicochemical properties, mechanical strength, and thermal behavior underscore the hydrogel's robustness and stability. Detecting minute MP particles remains challenging, prompting us to label MPs with Nile red for fluorescence microscopic analysis of their concentration and adsorption on the hydrogel. The catalytic properties of POM within the hydrogel facilitate UV-induced MP degradation, highlighting a sustainable solution. Our detailed kinetics and isotherm studies revealed pseudo-first-order and Langmuir models as fitting descriptors for MP adsorption, exhibiting a high maximum adsorption capacity (Qm). Notably, pGel@IPN achieved ∼95% and ∼93% removal efficiencies for polyvinyl chloride (PVC) and polypropylene (PP) MPs at pH ∼ 6.5, respectively, also demonstrating reusability for up to 5 cycles. Post-end-of-life, the spent adsorbent was efficiently upcycled into carbon nanomaterials, effectively removing the heavy metal Cr(VI), exemplifying circular economy principles. Our prepared hydrogel emerges as a potent solution for MP removal from water, promising effective mitigation of the emerging pollutants of MPs while ensuring sustainable environmental practices.

Graphical abstract: Polyoxometalate nanocluster-infused triple IPN hydrogels for excellent microplastic removal from contaminated water: detection, photodegradation, and upcycling

Supplementary files

Article information

Article type
Paper
Submitted
30 11月 2023
Accepted
04 2月 2024
First published
05 2月 2024

Nanoscale, 2024,16, 5188-5205

Polyoxometalate nanocluster-infused triple IPN hydrogels for excellent microplastic removal from contaminated water: detection, photodegradation, and upcycling

S. Dutta, A. Misra and S. Bose, Nanoscale, 2024, 16, 5188 DOI: 10.1039/D3NR06115A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements