Issue 91, 2018

Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity

Abstract

A complex [Au(NHC)2][Au(C[triple bond, length as m-dash]N)2] double salt exhibits polymorphic crystalline structures with distinct phosphorescence and variations at Au⋯Au distances and ligand–ligand torsion angles. This serves as a model system correlating aurophilicity and low-energy charge-transfer electronic transitions and helps to understand the thermochromism and mechanochromism of the gold(I) complexes.

Graphical abstract: Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(i) double salt with infinite aurophilicity

Supplementary files

Article information

Article type
Communication
Submitted
29 6月 2018
Accepted
17 10月 2018
First published
17 10月 2018

Chem. Commun., 2018,54, 12844-12847

Correlating thermochromic and mechanochromic phosphorescence with polymorphs of a complex gold(I) double salt with infinite aurophilicity

Q. Liu, M. Xie, X. Chang, Q. Gao, Y. Chen and W. Lu, Chem. Commun., 2018, 54, 12844 DOI: 10.1039/C8CC05210G

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