Issue 1, 1989

On the stability and bonding in bis(η-arene)ianthanide complexes

Abstract

Cocondensation of atoms of the lanthanide elements with 1,3,5-tri-t-butylbenzene gives the thermally stable bis(η-arene)lanthanide(0) sandwich compounds for the lanthanides Nd, Tb, Dy, Ho, Er, and Lu, thermally unstable complexes for La, Pr and Sm, and unisolable materials for Ce, Eu, Tm, and Yb; a simple bonding model is proposed to account for the stability trends, and for the magnetism of the stable complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 53-55

On the stability and bonding in bis(η-arene)ianthanide complexes

D. M. Anderson, F. G. N. Cloke, P. A. Cox, N. Edelstein, J. C. Green, T. Pang, A. A. Sameh and G. Shalimoff, J. Chem. Soc., Chem. Commun., 1989, 53 DOI: 10.1039/C39890000053

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements