Issue 1, 1989

Synthesis and characterization of η6-Cr(CO)3-indenyl-η3-rhodium-η4-C8H12: an η36 co-ordination for the indenyl ligand

Abstract

Deprotonation of indene–tricarbonylchromium with KH in tetrahydrofuran at –40 °C gives the η6-tricarbonylchromium–indenyl anion which reacts with [Rh(CI)COD]2(COD = cyclo-octa-1,5-diene) to form [η6-Cr(CO)3-indenyl-η3-rhodium-η4- COD]; the same bimetallic complex is obtained by reaction of the rhodium dimer with the isomeric η5-indenyl-tricarbonylchromium anion.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 51-53

Synthesis and characterization of η6-Cr(CO)3-indenyl-η3-rhodium-η4-C8H12: an η36 co-ordination for the indenyl ligand

A. Ceccon, A. Gambaro, S. Santi, G. Valle and A. Venzo, J. Chem. Soc., Chem. Commun., 1989, 51 DOI: 10.1039/C39890000051

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