Dynamics of the alkyne → copper(I) interaction and its use in a heteroleptic four-component catalytic rotor

Suchismita Saha; Sohom Kundu; Pronay Kumar Biswas; Michael Bolte; Michael Schmittel

doi:10.1039/D2CC04497H

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Dynamics of the alkyne → copper(i) interaction and its use in a heteroleptic four-component catalytic rotor†

Suchismita Saha,^a Sohom Kundu,^a Pronay Kumar Biswas,^a Michael Bolte

^b and Michael Schmittel

*^a

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* Corresponding authors

^a Center of Micro and Nanochemistry and (Bio)Technology, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str. 2, Siegen D-57068, Germany
E-mail: schmittel@chemie.uni-siegen.de
Tel: +49(0) 2717404356

^b Institut für Organische Chemie und Chemische Biologie, Johann Wolfgang Goethe-Universität, Max-von-Laue Strasse 7, Frankfurt am Main D-60438, Germany

Abstract

The HETPYNE (HETeroleptic Phenanthroline and alkYNE metal) and DABCO·(zinc porphyrin)₂ interactions were used to assemble the four-component nanorotor ROT-1 that exhibited a highly dynamic alkyne → copper(I) dissociation (k₂₉₈ = 240 kHz) at 298 K. Quantitative click reaction transformed ROT-1 into the new rotor ROT-2 (k₂₉₈ = 77 kHz) with a triazole → copper(I) linkage thus opening perspectives for bioorthogonal click strategies to biohybrid machinery.

This article is part of the themed collection: Chemical Communications HOT Articles 2022

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DOI: https://doi.org/10.1039/D2CC04497H
Article type: Communication
Submitted: 12 8月 2022
Accepted: 28 10月 2022
First published: 07 11月 2022
This article is Open Access

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Chem. Commun., 2022,58, 13019-13022

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Dynamics of the alkyne → copper(I) interaction and its use in a heteroleptic four-component catalytic rotor

S. Saha, S. Kundu, P. K. Biswas, M. Bolte and M. Schmittel, Chem. Commun., 2022, 58, 13019 DOI: 10.1039/D2CC04497H

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Chemical Communications

Dynamics of the alkyne → copper(i) interaction and its use in a heteroleptic four-component catalytic rotor†

Abstract

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Dynamics of the alkyne → copper(I) interaction and its use in a heteroleptic four-component catalytic rotor

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