The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity

Paulina Maksym; Roksana Bernat; Kajetan Koperwas; Marcin Wojtyniak; Julita Piecha; Barbara Hachuła; Monika Geppert-Rybczyńska; Agnieszka Brzózka; Grzegorz D. Sulka; Magdalena Tarnacka; Marian Paluch; Kamil Kamiński

doi:10.1039/D2CC05250D

The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity†

Paulina Maksym,

*^ab Roksana Bernat,

^bc Kajetan Koperwas,

^bd Marcin Wojtyniak,^e Julita Piecha,^bd Barbara Hachuła,

^bc Monika Geppert-Rybczyńska,^bc Agnieszka Brzózka,^f Grzegorz D. Sulka,

^f Magdalena Tarnacka,

^bd Marian Paluch^bd and Kamil Kamiński^bd

Author affiliations

* Corresponding authors

^a Institute of Materials Engineering, University of Silesia, 75 Pulku Piechoty 1a Street, Chorzow 41-500, Poland
E-mail: paulina.maksym@us.edu.pl

^b Silesian Center of Education and Interdisciplinary Research, University of Silesia, 75 Pulku Piechoty 1A Street, Chorzow 41-500, Poland

^c Institute of Chemistry, University of Silesia, Szkolna 9 Street, Katowice 40-007, Poland

^d Institute of Physics, University of Silesia, 75 Pulku Piechoty 1 Street, Chorzow 41-500, Poland

^e Institute of Physics – Center for Science and Education, Silesian University of Technology, Krasińskiego 8 Street, Katowice 40-019, Poland

^f Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, Gronostajowa 2 Street, Krakow 30-387, Poland

Abstract

In this paper, efficient MMA photo O-ATRP protocols conducted inside nanoreactors varying in nanostructured interfaces are reported for the first time. We showed that the microstructure of recovered polymers could be easily tuned just by implementing a given type of nanochannel (d = 10, 19–28, 35, 160 nm).

Chemical Communications

The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity†

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The unique role of pore wall nanostructurization in the intrachannel photo-ATRP for fine-tuning PMMA tacticity

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