Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl

Jiajia Li; Mengmeng Zhang; Xiangqiang Pan; Zhengbiao Zhang; Sébastien Perrier; Jian Zhu; Xiulin Zhu

doi:10.1039/C9CC03317C

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Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl†

Jiajia Li,^a Mengmeng Zhang,^a Xiangqiang Pan,

*^a Zhengbiao Zhang,

*^a Sébastien Perrier,

^bcd Jian Zhu

*^a and Xiulin Zhu^a

Author affiliations

* Corresponding authors

^a State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China
E-mail: chemzhujian@suda.edu.cn, panxq@suda.edu.cn, zhangzhengbiao@suda.edu.cn
Fax: +86 512 65882787
Tel: +86 512 65880726

^b Department of Chemistry, The University of Warwick, Coventry CV4 7AL, UK

^c Faculty of Pharmacy and Pharmaceutical Sciences, Monash University, 381 Royal Parade, Parkville, Victoria 3052, Australia

^d Warwick Medical School, The University of Warwick, Coventry CV4 7AL, UK

Abstract

A robust method for preparing controlled poly(vinyl ethers) utilizing commercially available reagents under visible light is reported. Pentacarbonylbromomanganese (Mn(CO)₅Br), generated from the conventional photolysis of manganese carbonyl and halide abstraction, is considered as a catalyst to oxidize carbon radical to carbenium ion in this polymerization. Polymerization behavior including the effects of solvents and monomers have been investigated.

This article is part of the themed collection: SU 120: Celebrating 120 Years of Soochow University

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DOI: https://doi.org/10.1039/C9CC03317C
Article type: Communication
Submitted: 01 5月 2019
Accepted: 24 5月 2019
First published: 24 5月 2019

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Chem. Commun., 2019,55, 7045-7048

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Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl

J. Li, M. Zhang, X. Pan, Z. Zhang, S. Perrier, J. Zhu and X. Zhu, Chem. Commun., 2019, 55, 7045 DOI: 10.1039/C9CC03317C

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Chemical Communications

Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl†

Abstract

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Visible light induced controlled cationic polymerization by in situ generated catalyst from manganese carbonyl

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